Exam 15: Chemical Kinetics

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The isomerization of methylisonitrile to acetonitrile CH3NC(g)→ CH3CN(g) Is first order in CH3NC.The half life of the reaction is 5.20 × 101 s at 545 K.The rate constant when the initial [CH3NC] is 0.030 M is ________ The isomerization of methylisonitrile to acetonitrile CH<sub>3</sub>NC(g)→ CH<sub>3</sub>CN(g) Is first order in CH<sub>3</sub>NC.The half life of the reaction is 5.20 × 10<sup>1</sup> s at 545 K.The rate constant when the initial [CH<sub>3</sub>NC] is 0.030 M is ________   . .

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The decomposition of dinitrogen pentoxide is described by the chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g) If the rate of appearance of O2 is equal to 3.00 mol/min at a particular moment,what is the rate of disappearance of N2O5 at that moment?

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Match the following.
Ea
rate constant
n,in Rate = k[A]n
reaction order
A
frequency factor
Correct Answer:
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Premises:
Responses:
Ea
rate constant
n,in Rate = k[A]n
reaction order
A
frequency factor
t1/2
half-life
k
activation energy
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Given the following balanced equation,determine the rate of reaction with respect to [H2]. N2(g)+ 3 H2(g)→ 2 NH3(g)

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What is the overall order of the following reaction,given the rate law? NO(g)+ O3(g)→ NO2(g)+ O2(g)Rate = k[NO][O3]

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In the hydrogenation of double bonds,a catalyst is needed.In the last step,the reactants must escape from the surface into the gas phase.This step is known as

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Define the frequency factor.

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The isomerization of methylisonitrile to acetonitrile CH3NC(g)→ CH3CN(g) Is first order in CH3NC.The rate constant for the reaction is 9.45 × 10-5 The isomerization of methylisonitrile to acetonitrile CH<sub>3</sub>NC(g)→ CH<sub>3</sub>CN(g) Is first order in CH<sub>3</sub>NC.The rate constant for the reaction is 9.45 × 10<sup>-5</sup>   at 478 K.The half-life of the reaction when the initial [CH<sub>3</sub>NC] is 0.030 M is ________ s. at 478 K.The half-life of the reaction when the initial [CH3NC] is 0.030 M is ________ s.

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Biological catalysts that increase the rates of biochemical reactions are known as

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Identify the rate-determining step.

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What are the units of k in a first order reaction?

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What data should be plotted to show that experimental concentration data fits a first-order reaction?

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Which of the following statements is FALSE?

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Give the characteristic of a first order reaction having only one reactant.

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The decomposition of dinitrogen pentoxide is described by the chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g) If the rate of disappearance of N2O5 is equal to 1.60 mol/min at a particular moment,what is the rate of appearance of NO2 at that moment?

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Determine the rate law and the value of k for the following reaction using the data provided. S2O82⁻(aq)+ 3 I⁻(aq)→ 2 SO42⁻(g)+ I3⁻(aq)[S2O82⁻]i (M)[I⁻]i (M)Initial Rate 0)30 0.42 4.54 0)44 0.42 6.65 0)44 0.21 3.33

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Carbon-14 has a half-life of 5720 years and this is a first order reaction.If a piece of wood has converted 75% of the carbon-14,then how old is it?

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What data should be plotted to show that experimental concentration data fits a second-order reaction?

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What is the overall reaction order for the reaction that has the rate law: Rate = k[O2] [NO ]2?

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A reaction is found to have an activation energy of 108 kJ/mol.If the rate constant for this reaction is 4.60 × 10-6 s-1 at 275 K,what is the rate constant at 366 K?

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