Exam 10: Thermochemistry

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When 5.00 mol of benzene is vaporized at a constant pressure of 1.00 atm and at its normal boiling point of 80.1°C,169.5 kJ are absorbed and PΔV for the vaporization process is equal to 14.5 kJ then

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A piece of metal weighing 57.3 g is heated to a temperature of 88.0°C and is then immersed in 155 g of water at a temperature of 21.53°C.After equilibration the temperature is 24.72°C.If CH2O = 4.184 J/g°C,what is Cmetal?

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Using the following equation for the combustion of octane,calculate the amount of moles of carbon dioxide formed from 100.0 g of octane.The molar mass of octane is 114.33 g/mole.The molar mass of carbon dioxide is 44.0095 g/mole. 2 C8H18 + 25 O2 → 16 CO2 + 18 H2O ΔH°rxn = -11018 kJ

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At constant pressure,the combustion of 6.00 g of C4H10(g)releases 297 kJ of heat.What is ΔH for the reaction given below? 2 C4H10(g)+ 13 O2(g)→ 8 CO2(g)+ 10 H2O(l)

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Define molar heat capacity.

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Which of the following is TRUE if ΔEsys = - 115 J?

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For ?Esys to always be -,what must be TRUE?

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What volume of benzene (C6H6,d= 0.88 g/mL,molar mass = 78.11 g/mol)is required to produce 1.5 × 103 kJ of heat according to the following reaction? 2 C6H6(l)+ 15 O2(g)→ 12 CO2(g)+ 6 H2O(g)ΔH°rxn = -6278 kJ

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How much heat is absorbed/released when 25.00 g of NH3(g)reacts in the presence of excess How much heat is absorbed/released when 25.00 g of NH<sub>3</sub>(g)reacts in the presence of excess   (g)to produce NO(g)and H<sub>2</sub>O(l)according to the following chemical equation? 4 NH<sub>3</sub>(g)+ 5 O<sub>2</sub>(g)→ 4 NO(g)+ 6 H<sub>2</sub>O(l)ΔH° = 1168 kJ (g)to produce NO(g)and H2O(l)according to the following chemical equation? 4 NH3(g)+ 5 O2(g)→ 4 NO(g)+ 6 H2O(l)ΔH° = 1168 kJ

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Use the information provided to determine ΔH°rxn for the following reaction ΔH°f (kJ/mol)CH4(g)+ 4 Cl2(g)→ CCl4(g)+ 4 HCl(g)ΔH°rxn = ? CH4(g)-75 CCl4(g)-96 HCl(g)-92

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The specific heat capacity of liquid water is 4.18 J/g-K.How many joules of heat are needed to raise the temperature of 5.00 g of water from 25.1°C to 65.3°C?

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Use the information provided to determine ΔH°rxn for the following reaction ΔH°f (kJ/mol)CH4(g)+ 3 Cl2(g)→ CHCl3(l)+ 3 HCl(g)ΔH°rxn = ? CH4(g)-75 CHCl3(l)-134 HCl(g)-92

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How much energy is evolved during the reaction of 51.2 g of Al,according to the reaction below? Assume that there is excess Fe2O3. Fe2O3(s)+ 2 Al(s)→ Al2O3(s)+ 2 Fe(s)ΔH°rxn = -852 kJ

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A sample of NI3 is contained in a piston and cylinder.The samples rapidly decomposes to form nitrogen gas and iodine gas,and releases 3.30 kJ of heat and does 950 J of work.What is ∆E?

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A 21.8 g sample of ethanol (C2H5OH)is burned in a bomb calorimeter,according to the following reaction.If the temperature rises from 25.0 to 62.3°C,determine the heat capacity of the calorimeter.The molar mass of ethanol is 46.07 g/mol. C2H5OH(l)+ 3 O2(g)→ 2 CO2(g)+ 3 H2O(g)ΔH°rxn = -1235 kJ

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The specific heat capacity of methane gas is 2.20 J/g-K.How many joules of heat are needed to raise the temperature of 5.00 g of methane from 36.0°C to 75.0°C?

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Calculate the kinetic energy of a 150 g baseball moving at a speed of 39.m/s ( 87 mph).

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Which of the following is NOT a standard state?

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All the following are state functions EXCEPT

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In the presence of excess oxygen,methane gas burns in a constant-pressure system to yield carbon dioxide and water: In the presence of excess oxygen,methane gas burns in a constant-pressure system to yield carbon dioxide and water:   (g)+   (g)→   (g)+   O(l)ΔH = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.70 g of methane is combusted at constant pressure. (g)+ In the presence of excess oxygen,methane gas burns in a constant-pressure system to yield carbon dioxide and water:   (g)+   (g)→   (g)+   O(l)ΔH = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.70 g of methane is combusted at constant pressure. (g)→ In the presence of excess oxygen,methane gas burns in a constant-pressure system to yield carbon dioxide and water:   (g)+   (g)→   (g)+   O(l)ΔH = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.70 g of methane is combusted at constant pressure. (g)+ In the presence of excess oxygen,methane gas burns in a constant-pressure system to yield carbon dioxide and water:   (g)+   (g)→   (g)+   O(l)ΔH = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.70 g of methane is combusted at constant pressure. O(l)ΔH = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.70 g of methane is combusted at constant pressure.

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