Exam 15: The Laws of Thermodynamics

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If the efficiency of a Carnot engine were to be 100%100 \% , the heat sink would have to be

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The figure shows a pVp V diagram for 8.3 g8.3 \mathrm {~g} of ideal nitrogen gas N2\mathrm { N } _ { 2 } in a sealed container. The temperature of state 1 is 59∘C59 ^ { \circ } \mathrm { C } , the atomic mass of the nitrogen atom is 14 g/mol14 \mathrm {~g} / \mathrm { mol } , and R=8.31 J/molR = 8.31 \mathrm {~J} / \mathrm { mol } - K. What are (a) pressure p1p _ { 1 } and (b) temperature T2T _ { 2 } ?  The figure shows a  p V  diagram for  8.3 \mathrm {~g}  of ideal nitrogen gas  \mathrm { N } _ { 2 }  in a sealed container. The temperature of state 1 is  59 ^ { \circ } \mathrm { C } , the atomic mass of the nitrogen atom is  14 \mathrm {~g} / \mathrm { mol } , and  R = 8.31 \mathrm {~J} / \mathrm { mol }  - K. What are (a) pressure  p _ { 1 }  and (b) temperature  T _ { 2 }  ?

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A 40.0-L container is divided into two equal parts by a rubber membrane. One half of the container has 1.501.50 moles of an ideal monatomic gas at 250 K250 \mathrm {~K} , and the other half is a vacuum. The container is well insulated, so there is no exchange of heat with the surroundings. The membrane breaks, and eventually the gas reaches a new equilibrium condition occupying the entire volume. What is the final temperature of the gas?

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What is the change in entropy of the ice when a 0.050−kg0.050 - \mathrm { kg } ice cube at 0∘C0 ^ { \circ } \mathrm { C } melts? The latent heat of fusion for water is 80cal/g80 \mathrm { cal } / \mathrm { g } .

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An ideal gas undergoes the process a→b→c→aa \rightarrow b \rightarrow c \rightarrow a shown in the pVp V diagram. In the figure, Pa=PC=P _ { a } = P _ { C } = 240kPa,Vb=Vc=40 L,Va=15 L240 \mathrm { kPa } , V _ { b } = V _ { c } = 40 \mathrm {~L} , V _ { a } = 15 \mathrm {~L} , and Pb=400kPaP _ { b } = 400 \mathrm { kPa } . How much heat is gained by the gas in this aa →b→c→a\rightarrow b \rightarrow c \rightarrow a process?  An ideal gas undergoes the process  a \rightarrow b \rightarrow c \rightarrow a  shown in the  p V  diagram. In the figure,  P _ { a } = P _ { C } =   240 \mathrm { kPa } , V _ { b } = V _ { c } = 40 \mathrm {~L} , V _ { a } = 15 \mathrm {~L} , and  P _ { b } = 400 \mathrm { kPa } . How much heat is gained by the gas in this  a   \rightarrow b \rightarrow c \rightarrow a  process?

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On a cold winter day, the outside temperature is −20∘C- 20 ^ { \circ } \mathrm { C } and the inside temperature is maintained at 20∘C20 ^ { \circ } \mathrm { C } . There is a net heat flow to the outside through the walls, roof, etc., of 25 kW25 \mathrm {~kW} . At what rate is the entropy of the air outside the house changing as a result of this process?

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A heat engine has an efficiency of 35.0% and receives 150 J of heat per cycle. (a) How much work does it do in each cycle? (b) How much heat does it "waste" in each cycle?

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The process shown on the pVp V diagram in the figure is  The process shown on the  p V  diagram in the figure is

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The figure shows a pVp V diagram of a gas for a complete cycle. During part bcb c of the cycle, 1190 J1190 \mathrm {~J} of heat flows into a system, and at the same time the system expands against a constant external pressure of 7.00×104 Pa7.00 \times 10 ^ { 4 } \mathrm {~Pa} as its volume increases from 0.0200 m30.0200 \mathrm {~m} ^ { 3 } to 0.0800 m30.0800 \mathrm {~m} ^ { 3 } . Calculate the change in internal (thermal) energy of the system during part bcb c of the cycle. If the change is nonzero, be sure to indicate whether the change is positive or negative.  The figure shows a  p V  diagram of a gas for a complete cycle. During part  b c  of the cycle,  1190 \mathrm {~J}  of heat flows into a system, and at the same time the system expands against a constant external pressure of  7.00 \times 10 ^ { 4 } \mathrm {~Pa}  as its volume increases from  0.0200 \mathrm {~m} ^ { 3 }  to  0.0800 \mathrm {~m} ^ { 3 } . Calculate the change in internal (thermal) energy of the system during part  b c  of the cycle. If the change is nonzero, be sure to indicate whether the change is positive or negative.

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An ideal Carnot engine operates between a warm reservoir at 233 K233 \mathrm {~K} and a colder reservoir. During each cycle, this engine extracts 15.0 J15.0 \mathrm {~J} of heat from the warm reservoir and does 4.0 J4.0 \mathrm {~J} of work. What is the temperature of the colder reservoir?

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A 0.42-kg quantity of ethanol, in the liquid state at its melting point of −114.4∘C- 114.4 ^ { \circ } \mathrm { C } , is frozen at atmospheric pressure. The heat of fusion of ethanol is 1.04×105 J/kg1.04 \times 10 ^ { 5 } \mathrm {~J} / \mathrm { kg } , and its molecular mass is 46.1 g/mol46.1 \mathrm {~g} / \mathrm { mol } . What is the change in the entropy of the ethanol as it freezes?

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During each cycle, a heat engine takes in 4.0 J of heat, does 1.0 J of work, and expels 3.0 J of heat. What is its efficiency?

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A heat engine absorbs 64 kcal of heat each cycle and exhausts 42 kcal. (a) What is the efficiency of this engine? (b) How much work does this engine do per cycle?

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An ideal gas undergoes an isothermal expansion. During this process, its entropy

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An ideal Carnot engine operates between a high temperature reservoir at 492 K492 \mathrm {~K} and a river with water at 290 K290 \mathrm {~K} . If it absorbs 4000 J4000 \mathrm {~J} of heat each cycle, how much work per cycle does it perform?

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During an isothermal process, 5.0 J5.0 \mathrm {~J} of heat is removed from an ideal gas. What is the change in internal (thermal) energy of the gas?

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When 1.0 kg1.0 \mathrm {~kg} of steam at 100∘C100 ^ { \circ } \mathrm { C } condenses to water at 100∘C100 ^ { \circ } \mathrm { C } , what is the change in entropy of the steam? The latent heat of vaporization of water is 22.6×105 J/kg22.6 \times 10 ^ { 5 } \mathrm {~J} / \mathrm { kg } .

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A gas is taken through the cycle shown in the pVp V diagram in the figure. During one cycle, how much work is done by the gas?  A gas is taken through the cycle shown in the  p V  diagram in the figure. During one cycle, how much work is done by the gas?

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