Exam 14: Chemical Equilibrium

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The equilibrium constant is equal to 5.00 L mol-1 at 1300 K for the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g) If initial concentrations are [SO2] = 6.00 mol L-1, [O2] = 0.45 mol L-1, and [SO3] = 9.00 mol L-1, the system is ________.

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The following reaction is exothermic. Which change will shift the equilibrium to the left? 2SO2(g) + O2(g) ⇌ 2SO3(g)

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Match the following. -K << 1

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Consider the following reaction at equilibrium. What effect will reducing the pressure of the reaction mixture have on the system? Xe(g) + 2F2(g) ⇌ XeF4(g)

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium concentration of SO2(g). 2SO2(g) + O2(g) ⇌ 2SO3(g) Kc = 1.7 × 108 M-1 [SO3]eq = 0.0034 mol L-1 [O2]eq = 0.0018 mol L-1

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In a reaction mixture containing reactants and products, each at a concentration of 1 mol L-1, what is the value of Q?

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For the isomerization reaction: butane ⇌ isobutane Kp equals 25.0 at 500 °C. If the initial pressures of butane and isobutane are 20.0 atm and 0.0 atm, respectively, what are the pressures of the two gases at equilibrium?

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What is the implication of Q = K?

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Consider the following reaction at equilibrium. What effect will removing H2O have on the system? 2H2S(g) + 3O2(g) ⇌ 2H2O(g) + 2SO2(g)

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Express the equilibrium constant for the following reaction: KClO3(s) ⇌ KClO(s) + O2(g)

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Consider the following reaction and its equilibrium constant: SO2(g) + NO2(g) ⇌ SO3(g) + NO(g) Kc = 0.33 A reaction mixture contains 0.50 mol L-1 SO2, 0.25 mol L-1 NO2 , 0.50 mol L-1 SO3, and 1.0 mol L-1 NO. Which of the following statements is TRUE concerning this system?

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Match the following. -Q >> 1

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 mol L-1, [O2]eq = 4.1 mol L-1, [N2O]eq = 3.3 × 10-18 mol L-1. 2N2(g) + O2(g) ⇌ 2N2O(g)

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What is the implication of Q < K?

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Consider the following reaction: NO(g) + SO3(g) ⇌ NO2(g) + SO2(g) A reaction mixture initially contains 2.0 bar NO and 1.0 bar SO3. Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

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Consider the following reaction: COCl2(g) ⇌ CO(g) + Cl2(g) A reaction mixture initially contains 1.6 mol L-1 COCl2. Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4 M. Calculate this based on the assumption that the answer is negligible compared to 1.6.

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Consider the following reaction at equilibrium. What effect will adding more SO3 have on the system? SO2(g) + NO2(g) ⇌ SO3(g) + NO(g)

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Calculate P (NO)eq, if P(NOCl)eq = 0.33 bar, P(Cl2)eq = 0.50 bar, and Kp = 1.9 × 10-2 bar . 2NOCl(g) ⇌ 2NO(g) + Cl2(g)

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The The   for the reaction below is 1.49 × 10<sup>8</sup> bar<sup>-1</sup> at 100.0 °C: CO(g) +   (g) →   (g) In an equilibrium mixture of the three gases,   =   = 1.92 × 10<sup>-4</sup> bar. The partial pressure of the product, phosgene (   ), is ________ bar. for the reaction below is 1.49 × 108 bar-1 at 100.0 °C: CO(g) + The   for the reaction below is 1.49 × 10<sup>8</sup> bar<sup>-1</sup> at 100.0 °C: CO(g) +   (g) →   (g) In an equilibrium mixture of the three gases,   =   = 1.92 × 10<sup>-4</sup> bar. The partial pressure of the product, phosgene (   ), is ________ bar. (g) → The   for the reaction below is 1.49 × 10<sup>8</sup> bar<sup>-1</sup> at 100.0 °C: CO(g) +   (g) →   (g) In an equilibrium mixture of the three gases,   =   = 1.92 × 10<sup>-4</sup> bar. The partial pressure of the product, phosgene (   ), is ________ bar. (g) In an equilibrium mixture of the three gases, The   for the reaction below is 1.49 × 10<sup>8</sup> bar<sup>-1</sup> at 100.0 °C: CO(g) +   (g) →   (g) In an equilibrium mixture of the three gases,   =   = 1.92 × 10<sup>-4</sup> bar. The partial pressure of the product, phosgene (   ), is ________ bar. = The   for the reaction below is 1.49 × 10<sup>8</sup> bar<sup>-1</sup> at 100.0 °C: CO(g) +   (g) →   (g) In an equilibrium mixture of the three gases,   =   = 1.92 × 10<sup>-4</sup> bar. The partial pressure of the product, phosgene (   ), is ________ bar. = 1.92 × 10-4 bar. The partial pressure of the product, phosgene ( The   for the reaction below is 1.49 × 10<sup>8</sup> bar<sup>-1</sup> at 100.0 °C: CO(g) +   (g) →   (g) In an equilibrium mixture of the three gases,   =   = 1.92 × 10<sup>-4</sup> bar. The partial pressure of the product, phosgene (   ), is ________ bar. ), is ________ bar.

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In a reaction mixture containing only reactants, what is the value of Q?

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