Exam 14: Chemical Equilibrium

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 mol L-1, [HI]eq = 5.6 × 10-16 mol L-1, [Cl2]eq = 0.0019 mol L-1. 2HCl(g) + I2(s) ⇌ 2HI(g) + Cl2(g)

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Match the following. -Q > K

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Consider the following reaction at equilibrium. What effect will decreasing the temperature have on the system? CO2(g) + 2H2O(l) ⇌ CH4(g) + 2O2(g) ΔrH° = +890 kJ

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Which of the following statements is correct?

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Consider the following reaction: NO(g) + SO3(g) ⇌ NO2(g) + SO2(g) A reaction mixture initially contains 0.384 bar NO2 and 0.224 bar SO2. Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

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For which of the following reactions will Kc = Kp?

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At 900.0 K, the equilibrium constant (Kp) for the following reaction is 0.345 bar-1: At 900.0 K, the equilibrium constant (K<sub>p</sub>) for the following reaction is 0.345 bar<sup>-1</sup>:   +   (g) →   (g) At equilibrium, the partial pressure of   is 35.0 bar and that of   is 15.9 bar. The partial pressure of   is ________ bar. + At 900.0 K, the equilibrium constant (K<sub>p</sub>) for the following reaction is 0.345 bar<sup>-1</sup>:   +   (g) →   (g) At equilibrium, the partial pressure of   is 35.0 bar and that of   is 15.9 bar. The partial pressure of   is ________ bar. (g) → At 900.0 K, the equilibrium constant (K<sub>p</sub>) for the following reaction is 0.345 bar<sup>-1</sup>:   +   (g) →   (g) At equilibrium, the partial pressure of   is 35.0 bar and that of   is 15.9 bar. The partial pressure of   is ________ bar. (g) At equilibrium, the partial pressure of At 900.0 K, the equilibrium constant (K<sub>p</sub>) for the following reaction is 0.345 bar<sup>-1</sup>:   +   (g) →   (g) At equilibrium, the partial pressure of   is 35.0 bar and that of   is 15.9 bar. The partial pressure of   is ________ bar. is 35.0 bar and that of At 900.0 K, the equilibrium constant (K<sub>p</sub>) for the following reaction is 0.345 bar<sup>-1</sup>:   +   (g) →   (g) At equilibrium, the partial pressure of   is 35.0 bar and that of   is 15.9 bar. The partial pressure of   is ________ bar. is 15.9 bar. The partial pressure of At 900.0 K, the equilibrium constant (K<sub>p</sub>) for the following reaction is 0.345 bar<sup>-1</sup>:   +   (g) →   (g) At equilibrium, the partial pressure of   is 35.0 bar and that of   is 15.9 bar. The partial pressure of   is ________ bar. is ________ bar.

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The equilibrium constant is given for one of two reactions below. Determine the value of the missing equilibrium constant. N2O4(g) ⇌ 2NO2(g) K = 1.46 3N2O4(g) ⇌ 6NO2(g) K = ?

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Consider the following reaction: CO2(g) + C(graphite) ⇌ 2CO(g) A reaction mixture initially contains 0.56 bar CO2 and 0.32 bar CO. Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25 bar.

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Consider the following reaction: NO(g) + SO3(g) ⇌ NO2(g) + SO2(g) A reaction mixture initially contains 2.0 bar NO2 and 1.0 bar SO2. Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

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At a certain temperature, Kc equals 1.40 × 102 M-1 for the reaction: 2CO(g) + O2(g) ⇌ 2CO2(g) If a 3.00 L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium, how many moles of CO are also present in the flask?

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How will equilibrium be affected for a reaction having the same number of moles of gaseous reactants and products if the pressure is increased?

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Consider the following reaction at equilibrium. What effect will adding CO2 have on the system? CO2(g) + C(graphite) ⇌ 2CO(g)

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The following reaction is exothermic. Which change will shift the equilibrium to the left? 2SO2(g) + O2(g) ⇌ 2SO3(g)

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Express the equilibrium constant for the following reaction: 2Na(s) + 2H2O(l) ⇌ 2NaOH(aq) + H2(g)

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Which of the following statements is FALSE?

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium concentration of NO2(g). N2O4(g) ⇌ 2NO2(g) Kc = 0.21 M [N2O4]eq = 1.82 mol L-1

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Consider the following reaction at equilibrium. What effect will increasing the pressure of the reaction mixture have on the system? CuS(s) + O2(g) ⇌ Cu(s) + SO2(g)

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At a certain temperature the equilibrium constant, Kc, equals 0.11 for the reaction: 2ICl(g) ⇌ I2(g) + Cl2(g) What is the equilibrium concentration of ICl if 0. 75 mol of I2 and 0. 75 mol of Cl2 are initially mixed in a 2.0 L flask?

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Express the equilibrium constant for the following reaction: N2(g) + 3H2(g) ⇔ 2NH3(g)

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