Exam 17: Gibbs Energy and Thermodynamics
Exam 1: Units of Measurement for Physical and Chemical Change192 Questions
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Exam 6: Thermochemistry161 Questions
Exam 7: The Quantum-Mechanical Model of the Atom170 Questions
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Exam 9: Chemical Bonding I: Lewis Theory155 Questions
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Exam 14: Chemical Equilibrium150 Questions
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Exam 17: Gibbs Energy and Thermodynamics134 Questions
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Exam 20: Organic Chemistry I: Structures109 Questions
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Exam 22: Biochemistry55 Questions
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Exam 24: Metals and Metallurgy49 Questions
Exam 25: Transition Metals and Coordination Compounds55 Questions
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Use the free energies of formation given below to calculate the equilibrium constant (K) for the following reaction at 298 K: 2HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l) K = ?
ΔfG° (kJ mol-1) -110.9 87.6 51.3 -237.1
(Multiple Choice)
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Consider a reaction that has a positive ΔrH and a negative ΔrS. Which of the following statements is TRUE?
(Multiple Choice)
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Given the following equation, N2O(g) + NO2(g) → 3NO(g) ΔrG° = -23.0 kJ mol-1
Calculate ΔrGo for the following reaction:
3NO(g) → N2O(g) + NO2(g)
(Multiple Choice)
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Determine the temperature of a reaction if ΔrG = 42.5 kJ mol-1, ΔrG° = 18.6 kJ mol-1, and Q = 17.7
(Multiple Choice)
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Place the following in order of decreasing molar entropy at 298 K. H2 Cl2 F2
(Multiple Choice)
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Consider a reaction that has a negative ΔrH and a negative ΔrS. Which of the following statements is TRUE?
(Multiple Choice)
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Consider the following reaction at constant pressure. Use the information here to determine the value of ΔSsurr at 298 K. Predict whether or not this reaction will be spontaneous at this temperature. N2(g) + 2O2(g) → 2NO2(g) ΔrH = +66.4 kJ
(Multiple Choice)
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Determine ΔrG° at 298 K using the following information: FeO(s) + CO(g) → Fe(s) + CO2(g) ΔrH°= -11.0 kJ mol-1; ΔrS°= -17.4 J K-1 mol-1
(Multiple Choice)
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Determine the temperature of a reaction if ΔrG° = 6.21 kJ mol-1, ΔrG = -8.34 kJ mol-1, and Q = 0.0100
(Multiple Choice)
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Calculate ΔrS° for the following reaction. The S° for each species is shown below the reaction. C2H2(g) + 2H2(g) → C2H6(g)
S°(J K-1 mol-1) 200.9 130.7 229.2
(Multiple Choice)
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Identify the compound with the standard Gibbs energy of formation equal to zero.
(Multiple Choice)
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Use Hess's law to calculate ΔrG° using the following information: CO(g) → C(s) + 1/2 O2(g) ΔrG° = ?
CO2(g) → C(s) + O2(g) ΔrG° = +394.4 kJ mol-1
CO(g) + 1/2 O2(g) → CO2(g) ΔrG° = -257.2 kJ mol-1
(Multiple Choice)
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Place the following in order of increasing molar entropy at 298 K. CO2 C3H8 SO
(Multiple Choice)
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Determine the equilibrium constant for the following reaction at 549 K: CH2O(g) + 2H2(g) → CH4(g) + H2O(g) ΔrH° = -94.9 kJ mol-1; ΔrS°= -224.2 J K-1 mol-1
(Multiple Choice)
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Use the following thermodynamic values to calculate Δr
.
Δr
= +95 kJ
, Δr
= -157 J
, T = 298 K
(Multiple Choice)
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Determine ΔrG° at 298 K using the following information: 2CH4(g) → C2H6(g) + H2(g) ΔrH°= +64.6 kJ mol-1; ΔrS°= -12.7 J K-1 mol-1
(Multiple Choice)
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