Exam 17: Gibbs Energy and Thermodynamics

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Use the free energies of formation given below to calculate the equilibrium constant (K) for the following reaction at 298 K: 2HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l) K = ? ΔfG° (kJ mol-1) -110.9 87.6 51.3 -237.1

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Consider a reaction that has a positive ΔrH and a negative ΔrS. Which of the following statements is TRUE?

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Give the standard states for a gas, liquid, solid, and solution.

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Given the following equation, N2O(g) + NO2(g) → 3NO(g) ΔrG° = -23.0 kJ mol-1 Calculate ΔrGo for the following reaction: 3NO(g) → N2O(g) + NO2(g)

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Determine the temperature of a reaction if ΔrG = 42.5 kJ mol-1, ΔrG° = 18.6 kJ mol-1, and Q = 17.7

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Place the following in order of decreasing molar entropy at 298 K. H2 Cl2 F2

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Match the following. -Q > K

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Consider a reaction that has a negative ΔrH and a negative ΔrS. Which of the following statements is TRUE?

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Consider the following reaction at constant pressure. Use the information here to determine the value of ΔSsurr at 298 K. Predict whether or not this reaction will be spontaneous at this temperature. N2(g) + 2O2(g) → 2NO2(g) ΔrH = +66.4 kJ

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Determine ΔrG° at 298 K using the following information: FeO(s) + CO(g) → Fe(s) + CO2(g) ΔrH°= -11.0 kJ mol-1; ΔrS°= -17.4 J K-1 mol-1

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Determine the temperature of a reaction if ΔrG° = 6.21 kJ mol-1, ΔrG = -8.34 kJ mol-1, and Q = 0.0100

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Calculate ΔrS° for the following reaction. The S° for each species is shown below the reaction. C2H2(g) + 2H2(g) → C2H6(g) S°(J K-1 mol-1) 200.9 130.7 229.2

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Identify the compound with the standard Gibbs energy of formation equal to zero.

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Which of the following processes have a ΔrS = 0?

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Use Hess's law to calculate ΔrG° using the following information: CO(g) → C(s) + 1/2 O2(g) ΔrG° = ? CO2(g) → C(s) + O2(g) ΔrG° = +394.4 kJ mol-1 CO(g) + 1/2 O2(g) → CO2(g) ΔrG° = -257.2 kJ mol-1

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Which of the following is TRUE regarding allotropes?

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Place the following in order of increasing molar entropy at 298 K. CO2 C3H8 SO

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Determine the equilibrium constant for the following reaction at 549 K: CH2O(g) + 2H2(g) → CH4(g) + H2O(g) ΔrH° = -94.9 kJ mol-1; ΔrS°= -224.2 J K-1 mol-1

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Use the following thermodynamic values to calculate Δr Use the following thermodynamic values to calculate Δ<sub>r</sub> <sub> </sub>   . Δ<sub>r</sub> <sub> </sub>   = +95 kJ   , Δ<sub>r</sub> <sub> </sub>   = -157 J   , T = 298 K . Δr Use the following thermodynamic values to calculate Δ<sub>r</sub> <sub> </sub>   . Δ<sub>r</sub> <sub> </sub>   = +95 kJ   , Δ<sub>r</sub> <sub> </sub>   = -157 J   , T = 298 K = +95 kJ Use the following thermodynamic values to calculate Δ<sub>r</sub> <sub> </sub>   . Δ<sub>r</sub> <sub> </sub>   = +95 kJ   , Δ<sub>r</sub> <sub> </sub>   = -157 J   , T = 298 K , Δr Use the following thermodynamic values to calculate Δ<sub>r</sub> <sub> </sub>   . Δ<sub>r</sub> <sub> </sub>   = +95 kJ   , Δ<sub>r</sub> <sub> </sub>   = -157 J   , T = 298 K = -157 J Use the following thermodynamic values to calculate Δ<sub>r</sub> <sub> </sub>   . Δ<sub>r</sub> <sub> </sub>   = +95 kJ   , Δ<sub>r</sub> <sub> </sub>   = -157 J   , T = 298 K , T = 298 K

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Determine ΔrG° at 298 K using the following information: 2CH4(g) → C2H6(g) + H2(g) ΔrH°= +64.6 kJ mol-1; ΔrS°= -12.7 J K-1 mol-1

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