Exam 17: Gibbs Energy and Thermodynamics

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Calculate ΔrG at 298 K under the conditions shown below for the following reaction: CaCO3(s) → CaO(s) + CO2(g) ΔrG° =+131.1 kJ mol-1 P(CO2) = 0.033 atm

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Calculate the equilibrium constant for the following reaction at 298 K: 2CO(g) + O2(g) → 2CO2(g)

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Match the following. -Q < 1

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How is a nonspontaneous process made spontaneous?

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Calculate ΔrG at 298 K under the conditions shown below for the following reaction: SO3(g) + H2O(g) → H2SO4(l) ΔrG°= -90.5 kJ mol-1 P(SO3) = 0.20 atm, P(H2O) = 0.88 atm

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Calculate ΔrG° at 298 K using the following information: 2H2S(g) + 3O2(g) → 2SO2(g) + 2H2O(g) ΔrG° = ? ΔfG°(kJ mol-1) -33.4 -300.1 -228.6

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Define the second law of thermodynamics.

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Determine the equilibrium constant for the following reaction at 298 K: SO3(g) + H2O(g) → H2SO4(l) ΔrG° = -90.5 kJ mol-1

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Why can't we say that a spontaneous reaction is a fast reaction?

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Which one of the following has the highest standard molar entropy, S°, at 25 °C?

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Calculate ΔrG for the evaporation of methanol at 25°C under nonstandard conditions when Calculate Δ<sub>r</sub>G for the evaporation of methanol at 25°C under nonstandard conditions when   = 10.0 mbar CH<sub>3</sub>OH(l) → CH<sub>3</sub>OH(g) = 10.0 mbar CH3OH(l) → CH3OH(g)

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Which of the following is TRUE if ln K is zero?

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The value of ΔfG° at 161.0 °C for the formation of phosphorus trichloride from its constituent elements, The value of Δ<sub>f</sub>G° at 161.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g) +   (g) →   (g) is ________ kJ mol<sup>-1</sup>. At 25.0 °C for this reaction, Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   is   . (g) + The value of Δ<sub>f</sub>G° at 161.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g) +   (g) →   (g) is ________ kJ mol<sup>-1</sup>. At 25.0 °C for this reaction, Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   is   . (g) → The value of Δ<sub>f</sub>G° at 161.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g) +   (g) →   (g) is ________ kJ mol<sup>-1</sup>. At 25.0 °C for this reaction, Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   is   . (g) is ________ kJ mol-1. At 25.0 °C for this reaction, ΔfH° is -720.5 kJ mol-1 and The value of Δ<sub>f</sub>G° at 161.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g) +   (g) →   (g) is ________ kJ mol<sup>-1</sup>. At 25.0 °C for this reaction, Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   is   . is The value of Δ<sub>f</sub>G° at 161.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g) +   (g) →   (g) is ________ kJ mol<sup>-1</sup>. At 25.0 °C for this reaction, Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   is   . .

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Which of the following is TRUE if ln K is negative?

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Calculate ΔrG at 298 K under the conditions shown below for the following reaction: 2Hg(g) + O2(g) → 2HgO(s) ΔG° = -180.8 kJ mol-1 P(Hg) = 0.025 atm, P(O2) = 0.037 atm

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Determine the equilibrium constant for the following reaction at 298 K: Cl(g) + O3(g) → ClO(g) + O2(g) ΔrG° = - 34.5 kJ mol-1

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Below what temperature does the following reaction become nonspontaneous? 2HNO3(aq) + NO(g) → 3NO2(g) + H2O(l) ΔrH = +136.5 kJ; ΔrS = +287.5 J K-1 mol-1

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What is the sign of ΔSuniv for a biological system?

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Which one of the following has the lowest standard molar entropy, S°, at 25 °C?

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Identify the statement that is TRUE.

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