Exam 18: Electrochemistry

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Based on the following information, Cl2(g) + 2 e- → 2 Cl-(aq) E° = +1.36 V Mg2+(aq) + 2 e- → 2 Mg(s) E° = -2.37 V Which of the following chemical species is the strongest reducing agent?

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Which of the following is the strongest oxidizing agent?

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If the standard reduction potential of Zn is -0.76 V, which of the following statements about a cell whose half-cells are Zn2+/Zn and SHE is correct?

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The electrolysis of molten The electrolysis of molten   for 4.25 hr with an electrical current of 25.0 A produces   of aluminum metal. for 4.25 hr with an electrical current of 25.0 A produces The electrolysis of molten   for 4.25 hr with an electrical current of 25.0 A produces   of aluminum metal. of aluminum metal.

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Determine the cell notation for the redox reaction given below: Pb(s) + 2H⁺(aq) → Pb2+(aq) + H2(g)

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25 °C. (The equation is balanced.) Mg(s) + Cu2+(aq) → Cu(s) + Mg2+(aq) Mg2+(aq) + 2 e⁻ → Mg(s) E° = -2.38 V Cu2+(aq) + 2 e⁻ → Cu(s) E° = +0.34 V

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What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?

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Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [ Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.500 M and [   ] = 2.00 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V ] = 0.500 M and [ Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.500 M and [   ] = 2.00 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V ] = 2.00 M Mg(s) + Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.500 M and [   ] = 2.00 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V (aq) → Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.500 M and [   ] = 2.00 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V (aq) + Fe(s) E°(Mg2+/Mg) = -2.37 V and E°(Fe3+/Fe) = -0.036 V

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C. (The equation is balanced.) Pb2+(aq) + Mg(s) → Pb(s) + Mg2+(aq) Mg2+(aq) +2 e- →Mg(s) E°= -2.37 V Pb2+(aq) + 2e- → Pb(s) E°= -0.13 V

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Which of the following reactions would have the smallest value of K at 298 K?

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Use the provided reduction potentials to calculate ΔrG° for the following balanced redox reaction: Pb2+(aq) + Cu(s) → Pb(s) + Cu2+(aq) E°(Pb2+/Pb) = -0.13 V and E°(Cu2+/Cu) = +0.34 V

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Which of the following is the strongest reducing agent?

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For a galvanic cell that uses the following two half-reactions, Cr2O72-(aq) + 14H+(aq) + 6 e- → 2Cr3+(aq) + 7H2O(l) Pb(s) → Pb2+(aq) + 2 e- How many moles of Pb(s) are oxidized by three mol es of Cr2O72-?

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Use the tabulated half-cell potentials to calculate the equilibrium constant (K) for the following balanced redox reaction at 25 °C: Pb2+(aq) + Cu(s) → Pb(s) + Cu2+(aq) E°(Pb2+/Pb) = -0.13 V and E°(Cu2+/Cu) = +0.34 V

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What is undergoing oxidation in the redox reaction represented by the following cell notation? Pb(s) ∣ Pb2+(aq) What is undergoing oxidation in the redox reaction represented by the following cell notation? Pb(s) ∣ Pb<sup>2+</sup>(aq)   H<sup>+</sup>(aq) ∣ H<sub>2</sub>(g) ∣ Pt(s) H+(aq) ∣ H2(g) ∣ Pt(s)

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Match the following. -Q = K

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25 °C. (The equation is balanced.) 2 Ag+(aq) + Pb(s) → 2Ag(s) + Pb2+(aq) Ag+(aq) + e- → Ag(s) E°= 0.80 V Pb2+(aq) + 2 e- → Pb(s) E°= -0.13 V

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Determine which of the following pairs of reactants will result in a spontaneous reaction at 25 °C.

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Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [ Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.914 M and [   ] = 0.0230 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V ] = 0.914 M and [ Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.914 M and [   ] = 0.0230 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V ] = 0.0230 M Mg(s) + Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.914 M and [   ] = 0.0230 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V (aq) → Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [   ] = 0.914 M and [   ] = 0.0230 M Mg(s) +   (aq) →   (aq) + Fe(s) E°(Mg<sup>2+</sup>/Mg) = -2.37 V and E°(Fe<sup>3+</sup>/Fe) = -0.036 V (aq) + Fe(s) E°(Mg2+/Mg) = -2.37 V and E°(Fe3+/Fe) = -0.036 V

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The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) + The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +   (aq) →   (aq) +   (g) With   = 1.0 atm and [   ] = 1.0 mol L<sup>-1</sup>, the cell potential is 0.45 V. The concentration of   in the cathode compartment is ________ mol L<sup>-1</sup>. (aq) → The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +   (aq) →   (aq) +   (g) With   = 1.0 atm and [   ] = 1.0 mol L<sup>-1</sup>, the cell potential is 0.45 V. The concentration of   in the cathode compartment is ________ mol L<sup>-1</sup>. (aq) + The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +   (aq) →   (aq) +   (g) With   = 1.0 atm and [   ] = 1.0 mol L<sup>-1</sup>, the cell potential is 0.45 V. The concentration of   in the cathode compartment is ________ mol L<sup>-1</sup>. (g) With The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +   (aq) →   (aq) +   (g) With   = 1.0 atm and [   ] = 1.0 mol L<sup>-1</sup>, the cell potential is 0.45 V. The concentration of   in the cathode compartment is ________ mol L<sup>-1</sup>. = 1.0 atm and [ The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +   (aq) →   (aq) +   (g) With   = 1.0 atm and [   ] = 1.0 mol L<sup>-1</sup>, the cell potential is 0.45 V. The concentration of   in the cathode compartment is ________ mol L<sup>-1</sup>. ] = 1.0 mol L-1, the cell potential is 0.45 V. The concentration of The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +   (aq) →   (aq) +   (g) With   = 1.0 atm and [   ] = 1.0 mol L<sup>-1</sup>, the cell potential is 0.45 V. The concentration of   in the cathode compartment is ________ mol L<sup>-1</sup>. in the cathode compartment is ________ mol L-1.

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