Exam 6: Thermochemistry Energy Flow and Chemical Change

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Use Hess's Law to calculate the enthalpy change for the reaction WO3(s) + 3H2(g) → W(s) + 3H2O(g) From the following data: 2W(s) + 3O2(g) → 2WO3(s) ΔH = -1685.4 kJ 2H2(g) + O2(g) → 2H2O(g) ΔH = -477.84 kJ

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Ethanol, C2H5OH, is being promoted as a clean fuel and is used as an additive in many gasoline mixtures. Calculate the ΔH°rxn for the combustion of ethanol. (ΔH°f [C2H5OH(l)] = -277.7 kJ/mol; ΔH°f [CO2(g)] = -393.5 kJ/mol; ΔH°f [H2O(g)] = -241.8 kJ/mol)

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For all processes, both q and ΔE will have the same sign.

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In which one of the following processes is ΔH = ΔE?

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Which one of the following relationships is always correct?

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A system that does no work but that transfers heat to the surroundings has

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Natural gas, or methane, is an important fuel. Combustion of one mole of methane releases 802.3 kilojoules of energy. How much energy does that represent in kilocalories?

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The Starship Enterprise is caught in a time warp and Spock is forced to use the primitive techniques of the 20th century to determine the specific heat capacity of an unknown mineral. The 307-g sample was heated to 98.7°C and placed into a calorimeter containing 72.4 g of water at 23.6°C. The heat capacity of the calorimeter was 15.7 J/K. The final temperature in the calorimeter was 32.4°C. What is the specific heat capacity of the mineral?

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In a reaction with high energy reactants and low energy products, q is negative.

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In which one of the following reactions would you expect ΔH to be substantially greater than ΔE (i.e., ΔH > ΔE)?

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When Karl Kaveman adds chilled grog to his new granite mug, he removes 10.9 kJ of energy from the mug. If it has a mass of 625 g and was at 25°C, what is its new temperature? Specific heat capacity of granite = 0.79 J/(g·K)

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For which one of the following reactions will ΔH be approximately (or exactly) equal to ΔE?

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