Exam 6: Thermochemistry Energy Flow and Chemical Change

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If, as a pioneer, you wished to warm your room by taking an object heated on top of a pot-bellied stove to it, which of the following 15-pound objects, each heated to 100°C, would be the best choice? The specific heat capacity (in J/(g·K)) for each substance is given in parentheses. Iron (0.450), copper (0.387), granite (0.79), gold (0.129), water (4.18).

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The only way in which a system can do work on the surroundings is by expansion against the external pressure.

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An important step in the synthesis of nitric acid is the conversion of ammonia to nitric oxide. 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g) Calculate ΔH°rxn for this reaction. ΔH°f [NH3(g)] = -45.9 kJ/mol; ΔH°f [NO(g)] = 90.3 kJ/mol; ΔH°f [H2O(g)] = -241.8 kJ/mol

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A system absorbs 21.6 kJ of heat while performing 6.9 kJ of work on the surroundings. If the initial internal energy, E, is 61.2 kJ, what is the final value of E?

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Standard heats (enthalpies) of formation of compounds, ΔH°f, may be positive or negative.

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Which one of the following is not a correct formation reaction? (products are correct)

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Your favorite candy bar, Gummy Beakers, contains 1.2 × 106 J of energy while your favorite soft drink, Bolt, contains 6.7 × 105 J. If you eat two packs of Gummy Beakers a day and drink 3 cans of Bolt, what percent of your 2000 Calorie daily food intake is left for broccoli, beans, beef, etc.?

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Calculate the enthalpy change for the reaction NO(g) + O(g) → NO2(g) From the following data: NO(g) + O3(g) → NO2(g) + O2(g) ΔH = -198.9 kJ O3(g) → 1.5O2(g) ΔH = -142.3 kJ O2(g) → 2O(g) ΔH = 495.0 kJ

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Which one of the following is a correct formation reaction?

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A system that undergoes an adiabatic change and does work on the surroundings has

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The compound carbon suboxide, C3O2, is a gas at room temperature. Use the data supplied to calculate the heat of formation of carbon suboxide. (Data: 2CO(g) + C(s) → C3O2(g) ΔH° = 127.3 kJ/mol And: ΔHf° of CO(g) = -110.5 kJ/mol)

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Ethylene glycol, used as a coolant in automotive engines, has a specific heat capacity of 2.42 J/(g·K). Calculate q when 3.65 kg of ethylene glycol is cooled from 132°C to 85°C.

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Which of the following is not a state function?

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In an endothermic reaction, in going from the reactants to the products at the same temperature, the value of q is negative.

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Combustion of a hydrocarbon will release more energy than combustion of an equal mass of carbohydrate because

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In a phase change of water between the liquid and the gas phases, 770.1 kJ of energy was released by the system. What was the product, and how much of it was formed in the phase change? (Data: H2O(l) → H2O(g) ΔH = 44.01 kJ/mol.)

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Calculate the ΔH°rxn for the following reaction. (ΔH°f [AsH3(g)] = 66.4 kJ/mol; ΔH°f [H3AsO4(aq)] = -904.6 kJ/mol; ΔH°f [H2O(l)] = -285.8 kJ/mol) H3AsO4(aq) + 4H2(g) → AsH3(g) + 4H2O(l)

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A system expands from a volume of 1.00 L to 2.00 L against a constant external pressure of 1.00 atm. The work (w) done by the system, in J, is

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A backpacker collects snow at 0°C, and places it in a cooking pot on a camp stove. It takes 643 kJ of heat energy to melt the snow and bring the water to boiling. Assuming no heat loss, and neglecting the specific heat capacity of the pot, calculate the mass of snow that the backpacker collected. (Data: specific heat capacity of liquid water, c = 4.18 J/g·K; and: H2O(s) → H2O(l) ΔH = ΔHfusion = 6.02 kJ/mol)

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A Snickers® candy bar contains 280 Calories, of which the fat content accounts for 120 Calories. What is the energy of the fat content, in kJ?

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