Exam 6: Thermochemistry Energy Flow and Chemical Change
Exam 1: Keys to Studying Chemistry Definitions, Units, and Problem Solving71 Questions
Exam 2: The Components of Matter100 Questions
Exam 3: Stoichiometry of Formulas and Equations70 Questions
Exam 4: Three Major Classes of Chemical Reactions111 Questions
Exam 5: Gases and the Kinetic-Molecular Theory97 Questions
Exam 6: Thermochemistry Energy Flow and Chemical Change72 Questions
Exam 7: Quantum Theory and Atomic Structure69 Questions
Exam 8: Electron Configuration and Chemical Periodicity77 Questions
Exam 9: Models of Chemical Bonding61 Questions
Exam 10: The Shapes of Molecules98 Questions
Exam 11: Theories of Covalent Bonding48 Questions
Exam 12: Intermolecular Forces Liquids, Solids, and Phase Changes90 Questions
Exam 13: The Properties of Mixtures Solutions and Colloids96 Questions
Exam 14: Periodic Patterns in the Main-Group Elements102 Questions
Exam 15: Organic Compounds and the Atomic Properties of Carbon107 Questions
Exam 16: Kinetics Rates and Mechanisms of Chemical Reactions78 Questions
Exam 17: Equilibrium the Extent of Chemical Reactions97 Questions
Exam 18: Acid-Base Equilibria100 Questions
Exam 19: Ionic Equilibria in Aqueous Systems114 Questions
Exam 20: Thermodynamics Entropy, Free Energy, and Reaction Direction84 Questions
Exam 21: Electrochemistry Chemical Change and Electrical Work100 Questions
Exam 22: The Elements in Nature and Industry45 Questions
Exam 23: Transition Elements and Their Coordination Compounds82 Questions
Exam 24: Nuclear Reactions and Their Applications81 Questions
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If, as a pioneer, you wished to warm your room by taking an object heated on top of a pot-bellied stove to it, which of the following 15-pound objects, each heated to 100°C, would be the best choice? The specific heat capacity (in J/(g·K)) for each substance is given in parentheses. Iron (0.450), copper (0.387), granite (0.79), gold (0.129), water (4.18).
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(Multiple Choice)
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Correct Answer:
E
The only way in which a system can do work on the surroundings is by expansion against the external pressure.
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(True/False)
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Correct Answer:
False
An important step in the synthesis of nitric acid is the conversion of ammonia to nitric oxide. 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g)
Calculate ΔH°rxn for this reaction.
ΔH°f [NH3(g)] = -45.9 kJ/mol; ΔH°f [NO(g)] = 90.3 kJ/mol; ΔH°f [H2O(g)] = -241.8 kJ/mol
Free
(Multiple Choice)
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Correct Answer:
A
A system absorbs 21.6 kJ of heat while performing 6.9 kJ of work on the surroundings. If the initial internal energy, E, is 61.2 kJ, what is the final value of E?
(Multiple Choice)
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Standard heats (enthalpies) of formation of compounds, ΔH°f, may be positive or negative.
(True/False)
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Which one of the following is not a correct formation reaction? (products are correct)
(Multiple Choice)
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Your favorite candy bar, Gummy Beakers, contains 1.2 × 106 J of energy while your favorite soft drink, Bolt, contains 6.7 × 105 J. If you eat two packs of Gummy Beakers a day and drink 3 cans of Bolt, what percent of your 2000 Calorie daily food intake is left for broccoli, beans, beef, etc.?
(Multiple Choice)
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Calculate the enthalpy change for the reaction NO(g) + O(g) → NO2(g)
From the following data:
NO(g) + O3(g) → NO2(g) + O2(g) ΔH = -198.9 kJ
O3(g) → 1.5O2(g) ΔH = -142.3 kJ
O2(g) → 2O(g) ΔH = 495.0 kJ
(Multiple Choice)
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A system that undergoes an adiabatic change and does work on the surroundings has
(Multiple Choice)
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The compound carbon suboxide, C3O2, is a gas at room temperature. Use the data supplied to calculate the heat of formation of carbon suboxide. (Data: 2CO(g) + C(s) → C3O2(g) ΔH° = 127.3 kJ/mol
And: ΔHf° of CO(g) = -110.5 kJ/mol)
(Multiple Choice)
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Ethylene glycol, used as a coolant in automotive engines, has a specific heat capacity of 2.42 J/(g·K). Calculate q when 3.65 kg of ethylene glycol is cooled from 132°C to 85°C.
(Multiple Choice)
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In an endothermic reaction, in going from the reactants to the products at the same temperature, the value of q is negative.
(True/False)
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Combustion of a hydrocarbon will release more energy than combustion of an equal mass of carbohydrate because
(Multiple Choice)
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In a phase change of water between the liquid and the gas phases, 770.1 kJ of energy was released by the system. What was the product, and how much of it was formed in the phase change? (Data: H2O(l) → H2O(g) ΔH = 44.01 kJ/mol.)
(Multiple Choice)
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Calculate the ΔH°rxn for the following reaction. (ΔH°f [AsH3(g)] = 66.4 kJ/mol; ΔH°f [H3AsO4(aq)] = -904.6 kJ/mol; ΔH°f [H2O(l)] = -285.8 kJ/mol) H3AsO4(aq) + 4H2(g) → AsH3(g) + 4H2O(l)
(Multiple Choice)
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A system expands from a volume of 1.00 L to 2.00 L against a constant external pressure of 1.00 atm. The work (w) done by the system, in J, is
(Multiple Choice)
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A backpacker collects snow at 0°C, and places it in a cooking pot on a camp stove. It takes 643 kJ of heat energy to melt the snow and bring the water to boiling. Assuming no heat loss, and neglecting the specific heat capacity of the pot, calculate the mass of snow that the backpacker collected. (Data: specific heat capacity of liquid water, c = 4.18 J/g·K; and: H2O(s) → H2O(l) ΔH = ΔHfusion = 6.02 kJ/mol)
(Multiple Choice)
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A Snickers® candy bar contains 280 Calories, of which the fat content accounts for 120 Calories. What is the energy of the fat content, in kJ?
(Multiple Choice)
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