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Chemistry Study Set 4
Exam 15: Aqueous Equilibria: Acids and Bases
Path 4
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Question 81
Multiple Choice
What is the pH of a solution prepared by dissolving 0.30 grams of solid CaO (lime) in enough water to make 2.00 L of aqueous Ca(OH)
2
(limewater) ? CaO(s) + H
2
O(l) → Ca
2+
(aq) + 2 OH
-
(aq)
Question 82
Short Answer
At 50°C the value of K
w
is 5.5 × 10
-14
,and the pH of a neutral solution at 50°C is ________.
Question 83
Multiple Choice
The following pictures represent aqueous solutions of three acids HA (A = X,Y,or Z) ;water molecules have been omitted for clarity.
-Arrange the three acids in order of increasing acid strength.
Question 84
Short Answer
A 0.50 M KNO
2
solution will have a pH ________ seven.
Question 85
Multiple Choice
CO
2
reacts with H
2
O to form HCO
3
-
and H
+
.Which picture below correctly represents the curved arrow notation for the initial Lewis acid-Lewis base interaction in this reaction;what is the Lewis acid and the Lewis base?
(1) (2)
Question 86
Multiple Choice
Calculate the pH of a 0.20 M H
2
SO
3
solution that has the stepwise dissociation constants K
a1
= 1.5 × 10
-2
and K
a2
= 6.3 × 10
-8
.
Question 87
Multiple Choice
What is the pH of a 0.020 M Ba(OH)
2
solution?
Question 88
Multiple Choice
What is the pH of a 0.30 M pyridine solution that has a K
b
= 1.9 × 10
-9
? The equation for the dissociation of pyridine is C
5
H
5
N(aq) + H
2
O(l) ⇌ C
5
H
5
NH
+
(aq) + OH
-
(aq) .
Question 89
Short Answer
The acid strength of an oxoacid having the general formula H
n
YO
m
increases as the electronegativity of Y ________ and as the oxidation number of Y ________.
Question 90
Multiple Choice
What is the hydroxide ion concentration of a lye solution that has a pH of 13.20?
Question 91
Multiple Choice
The percent dissociation of acetic acid changes as the concentration of the acid decreases.A 100-fold decrease in acetic acid concentration results in a ________ fold ________ in the percent dissociation.
Question 92
Multiple Choice
From the following chemical reactions determine the relative Br∅nsted-Lowry base strengths (strongest to weakest) . HNO
3
(aq) + H
2
O(l) → H
3
O
+
(aq) + NO
3
-
(aq) HF(aq) + H
2
O(l) ⇌ H
3
O
+
(aq) + F
-
(aq)
Question 93
Multiple Choice
Calculate the hydroxide ion concentration in an aqueous solution that contains 3.50 × 10
-5
M in hydronium ion.
Question 94
Multiple Choice
A tablet containing 500.0 mg of aspirin (acetylsalicylic acid or HC
9
H
7
O
4
) was dissolved in enough water to make 100 mL of solution.Given that K
a
= 3.0 × 10
-4
for aspirin,what is the pH of the solution?
Question 95
Short Answer
Undersea flora prefer a maximum concentration of OH
-
of 1.58 × 10
-5
.The concentration of H
3
O
+
in the seawater is ________,and this solution is ________ (acidic,basic,neutral).