Exam 16: Acid-Base Equilibria

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What is the percent ionization of a solution prepared by dissolving 0.0175 mol of chloroacetic acid,(HC2H2O2Cl)in 1.30 L of water? For chloroacetic acid,Ka = 1.4 × 10-3.

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What is the equilibrium hydronium ion concentration of an initially 4.5 M solution of hypoiodous acid,HOI,at 25°C (Ka = What is the equilibrium hydronium ion concentration of an initially 4.5 M solution of hypoiodous acid,HOI,at 25°C (K<sub>a</sub> =   )? )?

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Consider the Ka values for the following acids: Cyanic acid,HOCN,3.5 × 10-4 Formic acid,HCHO2,1.7 × 10-4 Lactic acid,HC3H5O3,1.3 × 10-4 Propionic acid,HC3H5O2,1.3 × 10-5 Benzoic acid,HC7H5O2,6.3 × 10-5 Which has the strongest conjugate base?

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The _____ is the shift in an ionic equilibrium caused by the addition of a solute that provides an ion that takes part in the equilibrium.

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If 20 mL of 0.10 M NaOH is added to 30 mL of 0.20 M HC2H3O2,what is the pH of the resulting solution at 25°C? Ka for HC2H3O2 is 1.8 × 10-5 at 25°C.

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For which of the following equilibria does Kc correspond to the base-ionization constant,Kb,of HCO3-?

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A solution contains 10.mmol of H3PO4 and 5.0 mmol of NaH2PO4.How many milliliters of 0.10 M NaOH must be added to reach the second equivalence point of the titration of the H3PO4 with NaOH?

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For which of the following equilibria does Kc correspond to the acid-ionization constant,Ka,of HCO3-?

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The Ka for hydrofluoric acid is 6.8 × 10-4.What is Kb for the fluoride ion?

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Which of the following salts forms an acidic aqueous solution?

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A solution contains 0.08 M acetic acid,HC2H3O2 (Ka = 1.7 × 10−5 at 25°C),and 0.15 M sodium acetate,NaC2H3O2.What is the pH of the solution at 25°C?

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A 25.00-mL sample of propionic acid,HC3H5O2,of unknown concentration was titrated with 0.141 M KOH.The equivalence point was reached when 43.76 mL of base had been added.What is the hydroxide-ion concentration at the equivalence point? Ka for propionic acid is 1.3 × 10-5 at 25°C.

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Which of the following will give a buffer with a pH near 9.24 when the acid and conjugate base are mixed in equimolar proportions? Acid Ka NH4+ (from ammonia) 5)69 × 10-10 HC2H3O2 (acetic acid) 1)75 × 10-5 HF (hydrofluoric acid) 6)8 × 10-4 CH3CH2NH3+ (from ethylamine) 2)12 × 10-11

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15.0 mL of 0.50 M HCl is added to a 100.0-mL sample of 0.484 M HNO2 (Ka for HNO2 = 4.0 × 10-4).What is the equilibrium concentration of NO2- ions?

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Titration of 0.2834 g of an unknown monoprotic acid dissolved in 25.00 mL of water requires 29.83 mL of 0.1582 M NaOH to reach the endpoint.What is the molar mass of the acid?

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A 25.00-mL sample of propionic acid,HC3H5O2,of unknown concentration was titrated with 0.103 M KOH.The equivalence point was reached when 43.88 mL of base had been added.What was the original concentration of the propionic acid?

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Which of the following mixtures will be a buffer when dissolved in 1 L of water?

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A(n)_____ is a solution characterized by the ability to resist changes in pH when limited amounts of acid or base are added to it.

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Which of the following represents the usual relationship of acid-ionization constants for a triprotic acid?

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What is the hydronium-ion concentration of a solution that is formed by combining 600.mL of 0.30 M NaOH with 400.mL of 0.90 M HNO3 at 25°C?

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