Exam 8: Reaction Rates and Equilibrium

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Which is an incorrect statement when discussing molecular collisions leading to the chemical reaction, AB + CD → AD + CB?

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C

What would be the effect of doubling the pressure on the following equilibrium system? N2(g)+ 3F2(g) What would be the effect of doubling the pressure on the following equilibrium system? N<sub>2</sub>(g)+ 3F<sub>2</sub>(g)   2NF<sub>3</sub>(g) 2NF3(g)

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A

Which method can be used to product a timed-release medication?

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D

Decreasing the temperature will decrease the number of effective collisions.

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You've been told that 'when a change is made in any factor of an established equilibrium, the position of equilibrium will shift in a direction that will minimize or oppose the change.'  This is a statement of which of the following?

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You purchase a glow stick during an evening parade.  After it ends, your roommate tells you that if you place it in the freezer, it will glow for a longer time. Assuming she knows what she is talking about, why would this be true?

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CFC's such as CF2Cl2, are associated with the increase in chemical activity that degrades ozone. Which of the following relates to this phenomenon?

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Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH4 + H2O Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH<sub>4</sub> + H<sub>2</sub>O   CH<sub>3</sub>OH + H<sub>2</sub> + heat Indicate the effect of the changing condition on the position of equilibrium. Refer to Equilibrium. Remove H<sub>2</sub> from the mixture. CH3OH + H2 + heat Indicate the effect of the changing condition on the position of equilibrium. Refer to Equilibrium. Remove H2 from the mixture.

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The following reaction is observed in a lab experiment:    A + 2B → C + D In this experiment, it required 750 s for the concentration of C to change from 0.333 M to 0.750 M.  What is the rate of the reaction?

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A room filled with a 2:1 mixture of hydrogen and oxygen gases can be safely inhaled.  However, with a single spark, it can react explosively.  Since the explosion would be considered a spontaneous process, what did the spark provide?

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​ Explain the difference between a homogeneous and a heterogeneous catalyst.

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CFC's are in the environment because they were released into the atmosphere. What was the use of CFC's?

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Consider the following energy diagram. Which letter represents the activation energy for the forward reaction? Consider the following energy diagram. Which letter represents the activation energy for the forward reaction?

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The concept of entropy

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Which is assumed to be true in most explanations of how reactions occur?

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A reaction is spontaneous when the conditions are

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Based on the following equilibrium constants, which reaction essentially goes to completion? Based on the following equilibrium constants, which reaction essentially goes to completion?

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Which of the following products is not suitable to timed-release method for medications that are desired to have an extended effective level time?

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Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH4 + H2O Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH<sub>4</sub> + H<sub>2</sub>O   CH<sub>3</sub>OH + H<sub>2</sub> + heat Indicate the effect of the changing condition on the position of equilibrium. Refer to Equilibrium. Add a catalyst to the mixture. CH3OH + H2 + heat Indicate the effect of the changing condition on the position of equilibrium. Refer to Equilibrium. Add a catalyst to the mixture.

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Homogeneous catalysts are thought to function by

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