Exam 16: Aqueous Ionic Equilibrium

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What is the molar solubility of AgCl in 0. 10 mol L-1 NaCN if the colourless complex ion Ag(CN)2- forms? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(CN)2- is 1.0 × 1021.

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Formic acid (HCOOH, Ka = 1.8 × 10-4) is the principal component in the venom of stinging ants. What is the molarity of a formic acid solution if 25.00 mL of the formic acid solution requires 29.80 mL of 0.0567 mol L-1 NaOH to reach the equivalence point?

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 mol L-1 methylamine, CH3NH2, with 20.00 mL of 0.10 mol L-1 methylammonium chloride, CH3NH3Cl? Assume that the volume of the solutions are additive and that Kb = 3.70 × 10-4 for methylamine.

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Identify a good buffer.

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Calculate the mole ratio of HCOONa to HCOOH required to make a buffer with pH of 3.62. Ka of HCOOH is 1.8 × 10-4.

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The molar solubility of CuI is 2.26 × 10-6 mol L-1 in pure water. Calculate the Ksp for CuI.

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How many millilitres of 0.0890 mol L-1 NaOH are required to titrate 25.0 mL of 0.0680 How many millilitres of 0.0890 mol L<sup>-1</sup> NaOH are required to titrate 25.0 mL of 0.0680   to the equivalence point? to the equivalence point?

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Calculate the percent ionization of nitrous acid in a solution that is 0.210 mol L-1 in nitrous acid Calculate the percent ionization of nitrous acid in a solution that is 0.210 mol L<sup>-1</sup> in nitrous acid   and 0.290 mol L<sup>-1</sup> in potassium nitrite (   ). The acid dissociation constant of nitrous acid is  and 0.290 mol L-1 in potassium nitrite ( Calculate the percent ionization of nitrous acid in a solution that is 0.210 mol L<sup>-1</sup> in nitrous acid   and 0.290 mol L<sup>-1</sup> in potassium nitrite (   ). The acid dissociation constant of nitrous acid is  ). The acid dissociation constant of nitrous acid is Calculate the percent ionization of nitrous acid in a solution that is 0.210 mol L<sup>-1</sup> in nitrous acid   and 0.290 mol L<sup>-1</sup> in potassium nitrite (   ). The acid dissociation constant of nitrous acid is

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Describe the solubility of Al(OH)3 with respect to pH.

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A solution is prepared by dissolving 0.23 mol of formic acid and 0.27 mol of sodium formate in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of NaOH to this buffer solution causes the pH to increase slightly. The pH does not increase drastically because the NaOH reacts with the ________ present in the buffer solution. The A solution is prepared by dissolving 0.23 mol of formic acid and 0.27 mol of sodium formate in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of NaOH to this buffer solution causes the pH to increase slightly. The pH does not increase drastically because the NaOH reacts with the ________ present in the buffer solution. The   of formic acid is 1.8 × 10<sup>-4</sup>. of formic acid is 1.8 × 10-4.

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A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution after the addition of 50.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.

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Calculate the pH of a buffer that is 0.040 mol L-1 HF and 0.020 mol L-1 LiF. The Ka for HF is 3.5 × 10-4.

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A 100.0 mL sample of 0.180 mol L-1 HClO4 is titrated with 0.270 mol L-1 NaOH. Determine the pH of the solution after the addition of 75.0 mL of NaOH.

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What happens at high pH to aluminum hydroxide precipitate?

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 mol L-1 NH3 with 5.00 mL of 0.10 mol L-1 NH4Cl? Assume that the volume of the solutions are additive and that Kb = 1.8 × 10-5 for NH3.

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The titration of 80.0 mL of an unknown concentration H3PO4 solution requires 126 mL of 0.218 mol L-1 KOH solution. What is the concentration of the H3PO4 solution (in mol L-1)?

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Determine the molar solubility of PbSO4 in pure water. Ksp (PbSO4) = 1.82 × 10-8.

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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 mol L-1 NH4Cl with 100.0 mL of 0.20 mol L-1 NH3. The Kb for NH3 is 1.8 × 10-5.

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Identify the most commonly used indicator among the following five.

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Calculate the solubility (in g L-1) of silver carbonate in water at 25 °C if the Ksp for Calculate the solubility (in g L<sup>-1</sup>) of silver carbonate in water at 25 °C if the K<sub>sp</sub> for   is 8.4 ×   . is 8.4 × Calculate the solubility (in g L<sup>-1</sup>) of silver carbonate in water at 25 °C if the K<sub>sp</sub> for   is 8.4 ×   . .

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