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For Which of the Following Reactions Would the Transition State →\rightarrow

Question 15

Multiple Choice

For which of the following reactions would the transition state most resemble the products? The following bond dissociation energies may be useful. (CH3) 2CH-H CH3CH2CH2-H H-F
(413 kJ mol-1) (423 kJ mol-1) (570 kJ mol-1)
H-Cl H-Br
(432 kJ mol-1) (366 kJ mol-1)


A)
 For which of the following reactions would the transition state most resemble the products? The following bond dissociation energies may be useful. (CH<sub>3</sub>) <sub>2</sub>CH-H CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>-H H-F (413 kJ mol<sup>-1</sup>)  (423 kJ mol<sup>-1</sup>)  (570 kJ mol<sup>-1</sup>)  H-Cl H-Br (432 kJ mol<sup>-1</sup>)  (366 kJ mol<sup>-1</sup>)  A)    B)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + F·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HF C)    D)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Cl·  \rightarrow  CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HCl E)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Br·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HBr
B) CH3CH2CH3 + F· →\rightarrow CH3CH2CH2· + HF
C)
 For which of the following reactions would the transition state most resemble the products? The following bond dissociation energies may be useful. (CH<sub>3</sub>) <sub>2</sub>CH-H CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>-H H-F (413 kJ mol<sup>-1</sup>)  (423 kJ mol<sup>-1</sup>)  (570 kJ mol<sup>-1</sup>)  H-Cl H-Br (432 kJ mol<sup>-1</sup>)  (366 kJ mol<sup>-1</sup>)  A)    B)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + F·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HF C)    D)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Cl·  \rightarrow  CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HCl E)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Br·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HBr
D) CH3CH2CH3 + Cl· →\rightarrow CH3CH2CH2· + HCl
E) CH3CH2CH3 + Br· →\rightarrow CH3CH2CH2· + HBr

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